沉积岩中蒙脱石-伊利石混层矿物的SEM/EDAX分析   总被引：1，自引：1，他引：1  

奚可棠 《矿物学报》1986,(3)

本文利用扫描电子显微镜与X射线能量色散分析联合法,对沉积岩中蒙脱石-伊利石混层矿物进行系统微区成分分析,求出混合层中伊利石的百分含量。  相似文献   

SEM-EDX Characterisation of Tropospheric Aerosols in the Negev Desert (Israel)     

Sophie Sobanska  Cécile Coeur  Willy Maenhaut  Freddy Adams 《Journal of Atmospheric Chemistry》2003,44(3):299-322

Individual aerosol particles collected in the Negev desert in Israel during a summer and winter campaign in 1996–1997 were analysed by scanning electron microscopy with energy-dispersive X-ray analysis. Hierarchical cluster analysis was performed to interpret the data on the basis of particle diameter and composition. Eleven particle classes (groups) provided clues on sources and/or particle formation. The summer samples were enriched in sulphates and mineral dusts; the winter samples contained more sea salts, aged sea salts, and industrial particles. The fine size fraction below 1 m diameter was enriched in secondary particles and showed evidence of atmospheric processing. The secondary sulphate particles were mainly attributed to long-range transport. A regional conversion from calcite to calcium sulphate occurred during summer. Industrial particles originating from local pollution appeared during winter.  相似文献   

Hydrous olivine (Mg_{1? y?} Fe²⁺_y)_{2? x} ?v _x ? SiO₄H_{2 x} – a new DHMS phase of variable composition observed as nanometer-sized precipitations in mantle olivine     

N. R. Khisina  R. Wirth 《Physics and Chemistry of Minerals》2002,29(2):98-111

 An olivine grain from a peridotite nodule 9206 (Udachnaya kimberlite, Siberia) was investigated by TEM methods including AEM, HRTEM, SAED and EELS techniques. A previous study of the 9206 olivine sample revealed OH absorption bands in the IR spectrum and abundant nanometer-sized OH-bearing inclusions, of hexagonal-like or lamellar shape. Inclusions, which are several hundred nm in size, consist of 10 ? phase, talc and serpentine (chrysotile and lizardite). The lamellar (LI) and hexagon-like small inclusions of several ten nm in size (SI) are the topic of the present paper. AEM investigations of the inclusions reveal Mg, Fe and Si as cations only. The Mg/Si and Fe/Si atomic ratios are lower in the inclusions than in the host olivine. The Si concentration in the olivine host and both lamellar inclusions and small inclusions is the same. A pre-peak at 528eV was observed in EEL spectra of LI and SI, which is attributed to OH⁻ or Fe³⁺. From these data it is concluded that there is a OH⁻- or Fe³⁺-bearing cation-deficient olivine-like phase present. HRTEM lattice fringe images of LI and SI exhibit modulated band-like contrasts, which are superimposed onto the olivine lattice. Diffraction patterns (Fourier-transforms) of the HREM images as well as SAED patterns show that the band-like contrasts in HRTEM images of the inclusions are caused by periodic modulations of the olivine lattice. Three kinds of superperiodicity in the olivine structure such as 2a, 3a and 3c, were observed in SAED patterns. The corresponding olivine supercells labelled here as Hy-2a, Hy-3a and Hy-3c were derived. The M1-vacancies located in the (100) and (001) octahedral layers of the olivine lattice are suggested to form ordered arrays of planar defects (PD), which cause the band-like contrasts in HRTEM patterns as well as the superperiodicity in the SAED patterns. The vacancy concentrations as well as the chemical composition of Hy-2a, Hy-3a and Hy-3c olivine supercells were calculated using crystal chemical approaches, assuming either {(OH)^< _O−V^" _Me−(OH)^< _O}^↔, or {F e ^< _Fe −H _Me ^′}^↔ or {2F e ^< _Fe −V _Me ^"}^↔ point defect associates. The calculated theoretical compositions Mg_1.615Fe⁺² _0.135v_0.25SiO₄H_0.5 (Hy-2a) and Mg_1.54Fe²⁺ _0.12v_0.33SiO₄H_0.66 (Hy-3a and Hy-3c) are in a good agreement with the AEM data on inclusions. Hy-2a, Hy-3a and Hy-3c are considered to be a hydrous olivine with the extended chemical formula (Mg_1-yFe²⁺ _y)_2−xv_xSiO₄H_2x. The crystal structure of hydrous olivine is proposed to be a modular olivine structure with Mg-vacant modules. The crystal chemical formula of hydrous olivines in terms of a modular structure can be written as [MgSiO₄H₂] · 3[Mg_1.82Fe_0.18SiO₄] for Hy-2a, [MgSiO₄H₂] · 2[Mg_1.82Fe_0.18SiO₄] for Hy-3a and Hy-3c. Hydrous olivine is suggested to be exsolved from the olivine 9206, which has been initially saturated by OH-bearing point defects. The olivine 9206 hydration as well as the following exsolution of hydrous olivine inclusions is suggested to occur at high pressure-high temperature conditions of the upper mantle. Received: 15 January 2001 / Accepted: 2 July 2001  相似文献   

Preliminary Characterisation of New Glass Reference Materials (GSA-1G, GSC-1G, GSD-1G and GSE-1G) by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry Using 193 nm, 213 nm and 266 nm Wavelengths   总被引：5，自引：1，他引：5  

Marcel Guillong  Kathrin Hametner  Eric Reusser  Stephen A. Wilson  Detlef Günther 《Geostandards and Geoanalytical Research》2005,29(3):315-331

New glass reference materials GSA-1G, GSC-1G, GSD-1G and GSE-1G have been characterised using a prototype solid state laser ablation system capable of producing wavelengths of 193 nm, 213 nm and 266 nm. This system allowed comparison of the effects of different laser wavelengths under nearly identical ablation and ICP operating conditions. The wavelengths 213 nm and 266 nm were also used at higher energy densities to evaluate the influence of energy density on quantitative analysis. In addition, the glass reference materials were analysed using commercially available 266 nm Nd:YAG and 193 nm ArF excimer lasers. Laser ablation analysis was carried out using both single spot and scanning mode ablation. Using laser ablation ICP-MS, concentrations of fifty-eight elements were determined with external calibration to the NIST SRM 610 glass reference material. Instead of applying the more common internal standardisation procedure, the total concentration of all element oxide concentrations was normalised to 100%. Major element concentrations were compared with those determined by electron microprobe. In addition to NIST SRM 610 for external calibration, USGS BCR-2G was used as a more closely matrix-matched reference material in order to compare the effect of matrix-matched and non matrix-matched calibration on quantitative analysis. The results show that the various laser wavelengths and energy densities applied produced similar results, with the exception of scanning mode ablation at 266 nm without matrix-matched calibration where deviations up to 60% from the average were found. However, results acquired using a scanning mode with a matrix-matched calibration agreed with results obtained by spot analysis. The increased abundance of large particles produced when using a scanning ablation mode with NIST SRM 610, is responsible for elemental fractionation effects caused by incomplete vaporisation of large particles in the ICP.  相似文献   

ODP204航次天然气水合物的可能有利储层——浊积层   总被引：3，自引：1，他引：3  

龚建明  张莉  陈建文  Young-Joo LEE  王红霞  闫桂京 《现代地质》2005,19(1):21-25

为了解岩性在天然气水合物分布中的作用, 利用岩矿鉴定、扫描电镜和能谱法对ODP204航次的 4个站位 10个钻孔共计 115个沉积物样品进行分析, 发现沉积物中矿物成分基本相近, 以粘土矿物为主, 含少量以石英为主的陆源碎屑。样品中含有丰富的硅藻和有孔虫等微体化石, 可形成硅藻粘土—硅藻土、有孔虫硅藻土或凝灰质硅质生物粘土。石英碎屑大多呈棱角状, 粒径小、含量少, 同时, 样品中可见透镜体、团块或旋涡状层状结构以及杂乱堆积的斑杂构造。上述特征表明沉积物为含有大量深海或半深海的浊流沉积物或其夹层。由于钻井岩心中有相当部分的天然气水合物样品分布在上述沉积物中, 推断这些浊流沉积物很可能是ODP204航次天然气水合物的有利储层。  相似文献   

Seasonal variation of the total electron content, maximum electron density and equivalent slab thickness at a South-American station     

G.A. Mansilla  M. Mosert  R.G. Ezquer   《Journal of Atmospheric and Solar》2005,67(17-18):1687

Total electron content (TEC) and foF2 ionosonde data obtained at Tucumán (26.9°S; 65.4°W) from April 1982 to March 1983 (high solar activity period) are analyzed to show the seasonal variation of TEC, NmF2 (proportional to square of foF2) and the equivalent slab thickness EST. Bimonthly averages of the monthly median for January–February, April–May, July–August and October–November have been considered to represent summer, autumn, winter and spring seasons, respectively. The results show that the higher values of TEC and maximum electron density of F2-layer NmF2 are observed during the equinoxes (semiannual anomaly). During daytime, both in TEC and in NmF2 the seasonal or winter anomaly can be seen. At nighttime, this effect is not observed. Also, the observed NmF2 values are used to check the validity of International Reference Ionosphere (IRI) to predict the seasonal variability of this parameter. In general, it is found that averaged monthly medians (obtained with the IRI model) overestimate averaged monthly median data for some hours of the day and underestimate for the other hours.  相似文献   

The Magnetospheric cusps: A Summary     

T. A. Fritz  Q. G. Zong 《Surveys in Geophysics》2005,26(1-3):409-414

The polar cusps of the magnetosphere are key regions for the transfer of mass, momentum, and energy from the solar wind into the magnetosphere. Understaning these key regions and the dynamical interactions that occur there are fundamentally important to determining the physical nature of the magnetosphere. In this paper we try to summarize many of the conclusions reached in the papers of this special issue emphasizing the present concepts and definition of the cusp, what variations could be temporal structures and what could be spatial structures. We address the need for further measurements and the role of present and planned projects to address these needs.  相似文献   

吉林省地质灾害类型及防治对策探讨     

腾继奎 《吉林地质》1997,16(2):62-64

本文针对吉林省的地质灾害类型及各类地质灾害的成因，分布及其危害进行了论述。对其防治对策进行了探讨，提出了切合本省实际的五项防治措施。  相似文献   

煤中显微裂隙的成因类型及其研究意义   总被引：8，自引：0，他引：8  

张慧  王晓刚  员争荣  郝琦 《岩石矿物学杂志》2002,21(3):278-284

分析、归纳了大量的扫描电子显微镜观测结果，以煤岩学、构造地质学研究为基础，依据煤中显微裂隙的形态，大小、排列组合等发育特征，将内生裂隙进一步划分为失水裂隙，缩聚裂隙、静压裂隙，将外生裂隙进一步划分为张性裂隙，压性裂隙，剪性裂隙，松弛裂隙，描述了各类隙的发育特征，探讨了裂隙的演化，识别和影响裂隙发育的因素，裂隙成因类型的研究，有助于判断不同裂隙对煤储层渗透率的贡献。  相似文献   

Simultaneous radio and optical observations of the mid-latitude atmospheric response to a major geomagnetic storm of 6–8 April 2000     

E. L. Afraimovich  Ya. F. Ashkaliev  V. M. Aushev  A. B. Beletsky  V. V. Vodyannikov  L. A. Leonovich  O. S. Lesyuta  Yu. V. Lipko  A. V. Mikhalev  A. F. Yakovets 《Journal of Atmospheric and Solar》2002,64(18)

Basic properties of the mid-latitude traveling ionospheric disturbances (TIDs) during the maximum phase of a major magnetic storm of 6–8 April 2000 are shown. Total electron content (TEC) variations were studied by using data from GPS receivers located in Russia and Central Asia. The nightglow response to this storm at mesopause and termospheric altitudes was also measured by optical instruments FENIX located at the observatory of the Institute of Solar-Terrestrial Physics (51.9°N,103.0°E), and MORTI located at the observatory of the Institute of Ionosphere (43.2°N, 77.0°E). Observations of the O (557.7 and 630.0 nm) emissions originating from atmospheric layers centered at altitudes of 90 and 250 km were carried out at Irkutsk and of the O₂(b¹∑_g⁺−X³∑_g⁻) (0-1) emission originating from an atmospheric layer centered at altitude of 94 km was carried out at Almaty. Our radio and optical measurement network observed a storm-induced solitary large-scale wave with duration of 1 h and a wave front width of no less than 5000 km, while it traveled equatorward with a velocity of 200 m/s from 62°N to 38°N geographic latitude. The TEC disturbance, basically displaying an electron content depression in the maximum of the F2 region, reveals a good correlation with growing nightglow emission, the temporal shift between the TEC and emission variation maxima being different for different altitudes. A comparison of the auroral oval parameters with dynamic spectra of TEC variations and optical 630 nm emissions in the frequency range 0.4–4 mHz (250–2500 s periods) showed that as the auroral oval expands into mid-latitudes, also does the region with a developed medium-sale and small-scale TEC structure.  相似文献